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A series of neutral pincer Pt(II) chloride complexes 3–7 were first synthesized via the reaction of 1,3-bis(N-substituted benzimidazol-2′-yl) benzene (bzimb) ligands 2a–e with K2PtCl4 in refluxing ...
Synthetic protocols for a pyrrolide-centered ONO3– trianionic pincer-type ligand are presented. Treating (tBuO)3W≡CtBu with the proligand [pyr-ONO]H3 (2) results in the formation of the trianionic ...
William Shatner opened up about the "ups and downs" of living with tinnitus — which he was diagnosed with in the 1990s — in a candid new video Shatner said he was left with "permanent tinnitus ...
Pincer-type linear nitrosyl Rh(I) complexes, Rh(PCPtBu)(NO)][BF4] (2) and [Rh(PCPtBuCH2)(NO)][BF4] (8), are reported (PCPtBu = 1,3-bis[(di-tert-butylphosphino)methyl]-2,4,6-trimethylbenzene). Complex ...
Chiral Pt (II)/Pd (II) pincer complexes that show C–H⋯Cl hydrogen bonding: Synthesis and applications to catalytic asymmetric aldol and silylcyanation reactions.
Ten-year-old Jace Clement was celebrated during Star Wars Night at the ballpark. It was a night packed with baseball, lightsabers, and memories to last a lifetime.
Mariska Hargitay, known for her role as Olivia Benson on "Law & Order: SVU," has revealed when she believes Benson and Detective Elliot Stabler should get together.
Oxorhenium (V) complexes incorporating a N, N ′- (pyridine-2,6-diylbis (methylene))bis (2,6-dibenzhydryl-4-methylaniline), DPM DAP, pincer ligand are outlined. These complexes, with tris ...
Iron PCP Pincer Complexes in Three Oxidation States: Reversible Ligand Protonation To Afford an Fe (0) Complex with an Agostic C–H Arene Bond Daniel Himmelbauer ...
A square-planar Pt (II) complex with a pyridine-based pincer-type N-heterocyclic carbene ligand, [Pt II (C ∧ N ∧ C) (Cl)]Cl (C ∧ N ∧ C = 2,6-bis (1-butylimidazol-2-ylidenyl)pyridine), was synthesized ...
Australia, a land of stunning landscapes and extraordinary biodiversity, also hosts some of the most formidable creatures on the planet. While the country’s beaches, outback, and forests invite ...